銅元(yuan)素是一(yi)種(zhong)金(jin)屬化學元(yuan)素,也是人(ren)體所必須的(de)一(yi)種(zhong)微量元(yuan)素, 銅也是人(ren)類發現最(zui)早(zao)的(de)金(jin)屬之一(yi),是人(ren)類廣泛使(shi)用(yong)的(de)一(yi)種(zhong)金(jin)屬,常應用(yong)于電氣、輕工、機械制(zhi)造(zao)、建筑工業、國(guo)防工業等領域,在中國(guo)有色金(jin)屬材(cai)料(liao)的(de)消費(fei)中僅次于鋁。現在,我們就來了(le)解更多有關金(jin)屬銅的(de)知識吧。
銅(tong)(tong)(tong)(tong)(tong)(tong)是(shi)人類最早(zao)使(shi)用(yong)的(de)(de)(de)(de)金(jin)屬(shu)。早(zao)在(zai)史(shi)前時代,人們(men)就(jiu)開始采掘(jue)露天銅(tong)(tong)(tong)(tong)(tong)(tong)礦,并用(yong)獲取的(de)(de)(de)(de)銅(tong)(tong)(tong)(tong)(tong)(tong)制造武(wu)器、式(shi)具和(he)(he)(he)其(qi)他器皿,銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)使(shi)用(yong)對(dui)早(zao)期人類文(wen)明的(de)(de)(de)(de)進步影響深遠。銅(tong)(tong)(tong)(tong)(tong)(tong)是(shi)一(yi)種存(cun)在(zai)于地殼和(he)(he)(he)海洋中(zhong)的(de)(de)(de)(de)金(jin)屬(shu)。銅(tong)(tong)(tong)(tong)(tong)(tong)在(zai)地殼中(zhong)的(de)(de)(de)(de)含量(liang)約為(wei)0.01%,在(zai)個別銅(tong)(tong)(tong)(tong)(tong)(tong)礦床中(zhong),銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)含量(liang)可以達到3%~5%。自然(ran)界中(zhong)的(de)(de)(de)(de)銅(tong)(tong)(tong)(tong)(tong)(tong),多數以化(hua)合物(wu)(wu)即(ji)銅(tong)(tong)(tong)(tong)(tong)(tong)礦物(wu)(wu)存(cun)在(zai)。銅(tong)(tong)(tong)(tong)(tong)(tong)礦物(wu)(wu)與其(qi)他礦物(wu)(wu)聚合成銅(tong)(tong)(tong)(tong)(tong)(tong)礦石,開采出(chu)(chu)來的(de)(de)(de)(de)銅(tong)(tong)(tong)(tong)(tong)(tong)礦石,經過(guo)選礦而成為(wei)含銅(tong)(tong)(tong)(tong)(tong)(tong)品位較高的(de)(de)(de)(de)銅(tong)(tong)(tong)(tong)(tong)(tong)精礦。是(shi)唯一(yi)的(de)(de)(de)(de)能(neng)大量(liang)天然(ran)產出(chu)(chu)的(de)(de)(de)(de)金(jin)屬(shu),也存(cun)在(zai)于各種礦石(例(li)如黃銅(tong)(tong)(tong)(tong)(tong)(tong)礦、輝銅(tong)(tong)(tong)(tong)(tong)(tong)礦、斑銅(tong)(tong)(tong)(tong)(tong)(tong)礦、赤(chi)銅(tong)(tong)(tong)(tong)(tong)(tong)礦和(he)(he)(he)孔雀石)中(zhong),能(neng)以單質金(jin)屬(shu)狀(zhuang)態及黃銅(tong)(tong)(tong)(tong)(tong)(tong)、青(qing)銅(tong)(tong)(tong)(tong)(tong)(tong)和(he)(he)(he)其(qi)他合金(jin)的(de)(de)(de)(de)形(xing)態用(yong)于工(gong)業(ye)、工(gong)程技術和(he)(he)(he)工(gong)藝上。
銅是(shi)與人(ren)類關(guan)系非(fei)常密(mi)切的有(you)色(se)(se)金屬,被(bei)廣泛地應用(yong)于電氣、輕工、機械制(zhi)造、建筑工業(ye)、國(guo)防(fang)工業(ye)等領域(yu),在中(zhong)國(guo)有(you)色(se)(se)金屬材料的消(xiao)費(fei)中(zhong)僅次于鋁。銅是(shi)一(yi)種紅色(se)(se)金屬,同時也是(shi)一(yi)種綠(lv)色(se)(se)金屬。說它是(shi)綠(lv)色(se)(se)金屬,主要(yao)是(shi)因(yin)為它熔點較(jiao)低(di),容易再熔化、再冶煉,因(yin)而(er)回收(shou)利用(yong)相當地便宜。古代主要(yao)用(yong)于器皿、藝(yi)術品及(ji)(ji)武器鑄造,比(bi)較(jiao)有(you)名(ming)的器皿及(ji)(ji)藝(yi)術品如司母戊鼎、四羊方尊。
銅(tong)密(mi)度的定義:銅(tong)的質量與銅(tong)體(ti)積的比值就叫作銅(tong)密(mi)度。
銅密度符號和(he)單位:通常(chang)用“ρ”(讀做rōu)表示,單位為g/cm3,正確讀法是克每立方(fang)厘米(mi)。還(huan)有一種不常(chang)用的(de)單位是kg/dm3,讀作千(qian)克每立方(fang)分米(mi)。它們之(zhi)間的(de)換算關(guan)系:lg/cm3=1kg/dm3=103kg/m3。
銅密度的公式:
1.銅(tong)密度(du)的公(gong)式:ρ=m/V,ρ=dm/dV(ρ表(biao)示(shi)密度(du)、m表(biao)示(shi)質(zhi)量(liang)、V表(biao)示(shi)體積)
2.銅密度公式變形:V=m/ρ,m=ρV,m=∫ρ(V)dV。
3.質量(liang)m可以用(yong)天平測量(liang),液體(ti)和形狀不(bu)規則的固體(ti)的體(ti)積v可以用(yong)量(liang)筒或量(liang)杯測量(liang)。
4.物質的(de)(de)密度是(shi)一定的(de)(de),它不(bu)(bu)隨(sui)體積(ji)和(he)質量的(de)(de)變(bian)化而變(bian)化,不(bu)(bu)同牌(pai)號的(de)(de)銅(tong)密度也是(shi)不(bu)(bu)隨(sui)體積(ji)變(bian)化而變(bian)化的(de)(de)。
純(chun)銅密度(du)、黃銅密度(du)、青銅密度(du)、白銅密度(du):
1.純銅(tong),無氧銅(tong)的(de)密(mi)度是(shi)(shi)8.9(g/cm3),磷脫氧銅(tong)的(de)密(mi)度是(shi)(shi)8.89(g/cm3)。
2.加工黃銅的密度是(shi)8.5-8.8(g/cm3),鑄造黃銅的密度是(shi)7.7-8.55(g/cm3)。
3.加工(gong)青(qing)銅(tong)的(de)密度是7.5-8.9(g/cm3),鑄造青(qing)銅(tong)的(de)密度是7.45-9.54(g/cm3)。
4.白銅的密度是8.4-8.9(g/cm3)。
純銅
純銅:中國俗(su)稱‘紫銅’,日本(ben)與臺灣俗(su)稱‘紅(hong)銅’。
紅銅(tong)即純銅(tong),又名紫銅(tong),純銅(tong)密度為(wei)8.96,熔(rong)點(dian)為(wei)1083℃。具有(you)很好(hao)的導電(dian)性和(he)導熱性,塑性極(ji)好(hao),易(yi)于熱壓和(he)冷(leng)壓力加工,大量用(yong)于制造(zao)電(dian)線、電(dian)纜、電(dian)刷(shua)、電(dian)火花專用(yong)電(dian)蝕銅(tong)等要求導電(dian)性良好(hao)的產品。
因(yin)呈紫紅色而得名。它不一定是純銅(tong)(tong)(tong)(tong),有時還加入(ru)少量脫(tuo)氧元素(su)(su)或其他(ta)元素(su)(su),以改善材質和性(xing)能(neng),因(yin)此也歸入(ru)銅(tong)(tong)(tong)(tong)合金。中國紫銅(tong)(tong)(tong)(tong)加工材按成分可(ke)分為:普通(tong)紫銅(tong)(tong)(tong)(tong)(T1、T2、T3、T4)、無(wu)氧銅(tong)(tong)(tong)(tong)(TU1、TU2和高(gao)純、真空無(wu)氧銅(tong)(tong)(tong)(tong))、脫(tuo)氧銅(tong)(tong)(tong)(tong)(TUP、TUMn)、添加少量合金元素(su)(su)的特種銅(tong)(tong)(tong)(tong)(砷銅(tong)(tong)(tong)(tong)、碲銅(tong)(tong)(tong)(tong)、銀銅(tong)(tong)(tong)(tong))四類。
黃銅
黃銅(tong)(tong):銅(tong)(tong)鋅合金。
以鋅(xin)作主(zhu)要(yao)添加元(yuan)素的(de)(de)銅(tong)(tong)合金(jin),具有美觀的(de)(de)黃(huang)(huang)(huang)(huang)色(se),統(tong)稱(cheng)黃(huang)(huang)(huang)(huang)銅(tong)(tong)。銅(tong)(tong)鋅(xin)二(er)元(yuan)合金(jin)稱(cheng)普通黃(huang)(huang)(huang)(huang)銅(tong)(tong)或稱(cheng)簡單黃(huang)(huang)(huang)(huang)銅(tong)(tong)。三元(yuan)以上(shang)的(de)(de)黃(huang)(huang)(huang)(huang)銅(tong)(tong)稱(cheng)特殊(shu)黃(huang)(huang)(huang)(huang)銅(tong)(tong)或稱(cheng)復雜(za)黃(huang)(huang)(huang)(huang)銅(tong)(tong)。含鋅(xin)低於36%的(de)(de)黃(huang)(huang)(huang)(huang)銅(tong)(tong)合金(jin)由固溶(rong)(rong)體組成,具有良好的(de)(de)冷加工性能,如含鋅(xin)30%的(de)(de)黃(huang)(huang)(huang)(huang)銅(tong)(tong)常用來制作彈殼,俗稱(cheng)彈殼黃(huang)(huang)(huang)(huang)銅(tong)(tong)或七三黃(huang)(huang)(huang)(huang)銅(tong)(tong)。含鋅(xin)在36~42%之間(jian)的(de)(de)黃(huang)(huang)(huang)(huang)銅(tong)(tong)合金(jin)由和固溶(rong)(rong)體組成,其中(zhong)最常用的(de)(de)是含鋅(xin)40%的(de)(de)六(liu)四黃(huang)(huang)(huang)(huang)銅(tong)(tong)。
白銅
白銅:銅、鈷(gu)、鎳(nie)合金。
以鎳為主要添加元素的(de)(de)銅(tong)(tong)(tong)(tong)(tong)(tong)合(he)金。銅(tong)(tong)(tong)(tong)(tong)(tong)鎳二元合(he)金稱(cheng)普通白銅(tong)(tong)(tong)(tong)(tong)(tong);加有錳(meng)、鐵(tie)、鋅、鋁(lv)等(deng)元素的(de)(de)白銅(tong)(tong)(tong)(tong)(tong)(tong)合(he)金稱(cheng)復雜白銅(tong)(tong)(tong)(tong)(tong)(tong)。工(gong)(gong)業(ye)用白銅(tong)(tong)(tong)(tong)(tong)(tong)分為結構白銅(tong)(tong)(tong)(tong)(tong)(tong)和電(dian)(dian)工(gong)(gong)白銅(tong)(tong)(tong)(tong)(tong)(tong)兩(liang)大類。結構白銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)特點是機(ji)械性能和耐蝕性好,色(se)澤(ze)美觀。這種白銅(tong)(tong)(tong)(tong)(tong)(tong)廣泛用於制(zhi)造精密機(ji)械、化(hua)工(gong)(gong)機(ji)械和船舶構件。電(dian)(dian)工(gong)(gong)白銅(tong)(tong)(tong)(tong)(tong)(tong)一般有良好的(de)(de)熱電(dian)(dian)性能。錳(meng)銅(tong)(tong)(tong)(tong)(tong)(tong)、康銅(tong)(tong)(tong)(tong)(tong)(tong)、考銅(tong)(tong)(tong)(tong)(tong)(tong)是含錳(meng)量不同(tong)的(de)(de)錳(meng)白銅(tong)(tong)(tong)(tong)(tong)(tong),是制(zhi)造精密電(dian)(dian)工(gong)(gong)儀器、變(bian)阻(zu)器、精密電(dian)(dian)阻(zu)、應變(bian)片、熱電(dian)(dian)偶(ou)等(deng)用的(de)(de)材料。
青銅
青銅(tong):銅(tong)錫合金(jin)
原(yuan)指銅(tong)(tong)錫合金,后除黃銅(tong)(tong)、白(bai)銅(tong)(tong)以外的(de)銅(tong)(tong)合金均稱青銅(tong)(tong),并常(chang)在青銅(tong)(tong)名字前(qian)冠以第一主要添(tian)加元素的(de)名。錫青銅(tong)(tong)的(de)鑄(zhu)造(zao)性能(neng)、減(jian)摩性能(neng)好(hao)和機(ji)械性能(neng)好(hao),適合於制(zhi)(zhi)造(zao)軸(zhou)承(cheng)、蝸輪(lun)、齒輪(lun)等(deng)(deng)。鉛青銅(tong)(tong)是現代發動機(ji)和磨床廣泛使用的(de)軸(zhou)承(cheng)材料。鋁青銅(tong)(tong)強度高,耐(nai)磨性和耐(nai)蝕性好(hao),用於鑄(zhu)造(zao)高載荷(he)的(de)齒輪(lun)、軸(zhou)套、船用螺(luo)旋槳等(deng)(deng)。鈹青銅(tong)(tong)和磷青銅(tong)(tong)的(de)彈(dan)性極限高,導電(dian)性好(hao),適於制(zhi)(zhi)造(zao)精(jing)密彈(dan)簧和電(dian)接觸元件(jian),鈹青銅(tong)(tong)還用來(lai)制(zhi)(zhi)造(zao)煤礦、油庫等(deng)(deng)使用的(de)無火花工具。
銅的吸收
一(yi)般情況下,銅(tong)(tong)的(de)(de)攝入量嬰幼兒期為0.4~1.0mg/日,成人為1.5~3.omg/日,吸(xi)(xi)(xi)收率30~40%。胃(wei)、十二(er)指腸(chang)和小腸(chang)上部(bu)是(shi)銅(tong)(tong)的(de)(de)主(zhu)(zhu)要吸(xi)(xi)(xi)收部(bu)位,其腸(chang)吸(xi)(xi)(xi)收是(shi)主(zhu)(zhu)動吸(xi)(xi)(xi)收過程(cheng)。膜內外銅(tong)(tong)離子的(de)(de)轉運(yun)體為ATP酶(mei),依靠天冬氨酸殘基磷酸化供能(neng),能(neng)將主(zhu)(zhu)動吸(xi)(xi)(xi)收的(de)(de)銅(tong)(tong)與(yu)門靜脈(mo)側(ce)枝循環中(zhong)的(de)(de)白(bai)蛋白(bai)結合(he),運(yun)至肝臟進一(yi)步參(can)與(yu)代謝。
在人體的應用
銅(tong)(tong)是人體健康(kang)不(bu)可缺(que)少的(de)微(wei)量營養素,對于血液、中樞神(shen)經(jing)和免疫系(xi)統,頭(tou)發、皮膚和骨骼(ge)組織(zhi)以及(ji)腦子(zi)和肝、心等內臟的(de)發育(yu)和功能有重要(yao)影響。銅(tong)(tong)主要(yao)從日常(chang)飲食中攝入。世界衛生組織(zhi)建(jian)議,為了維持健康(kang),成人每公(gong)斤體重每天應攝入0.03毫克銅(tong)(tong)。孕婦和嬰幼兒應加(jia)倍。缺(que)銅(tong)(tong)會引起各種疾(ji)病(bing),可以服用含銅(tong)(tong)補劑和藥丸(wan)來加(jia)以補充。
銅(tong)在(zai)人體內含(han)量約100~150mg,血(xue)(xue)清銅(tong)正常值(zhi)100~120μg/dl,是(shi)人體中含(han)量位(wei)居第(di)二(er)的(de)必需微量元素(su)。含(han)銅(tong)的(de)酶有酪氨酸酶、單胺氧(yang)(yang)化酶、超氧(yang)(yang)化酶、超氧(yang)(yang)化物歧化酶、血(xue)(xue)銅(tong)藍蛋(dan)白等。銅(tong)對血(xue)(xue)紅(hong)蛋(dan)白的(de)形成(cheng)(cheng)起活(huo)化作(zuo)用,促進鐵的(de)吸收和(he)利(li)用,在(zai)傳遞電子、彈性蛋(dan)白的(de)合成(cheng)(cheng)、結締組織的(de)代謝(xie)(xie)、嘌呤代謝(xie)(xie)、磷脂及神經組織形成(cheng)(cheng)方面有重(zhong)要意義。
銅缺乏可(ke)引起如下疾(ji)病:
1.貧血
一般(ban)最常見的臨床(chuang)表現為頭暈、乏(fa)力、易倦、耳(er)鳴、眼(yan)花。皮膚(fu)黏膜及指(zhi)甲等顏色蒼白(bai),體(ti)力活(huo)動(dong)后(hou)感覺(jue)氣(qi)促(cu)、心(xin)(xin)悸。嚴重貧血時(shi),即(ji)使在(zai)休息(xi)時(shi)也出現氣(qi)短和心(xin)(xin)悸,在(zai)心(xin)(xin)尖和心(xin)(xin)底(di)部可聽到柔和的收(shou)縮(suo)期雜音。
2.骨(gu)骼改變
臨床表(biao)現為骨(gu)(gu)質疏(shu)松(song),易發(fa)生骨(gu)(gu)折。
3.銅與冠心病
4.銅與白癜(dian)風病
5.女性不(bu)孕(yun)癥
利用銅制品的相關屬性來生產銅制品
1、導線(xian)(xian)的(de)線(xian)(xian)心:用銅做導線(xian)(xian)即(ji)是導體(ti),導體(ti)的(de)性質是具有導電(dian)性。
2、各(ge)種電器(qi)(qi)中的(de)散熱器(qi)(qi):散熱器(qi)(qi)的(de)作用是用來(lai)散熱的(de),所(suo)以利用的(de)是銅的(de)導熱性。
3、各種裝飾的(de)(de)銅箔:能制成各種形狀銅箔,這是利用了銅的(de)(de)延(yan)展(zhan)性。
銅及其合金加工材
板材(cai)(cai)、帶(dai)材(cai)(cai)、箔材(cai)(cai)、排材(cai)(cai)、管材(cai)(cai)、棒材(cai)(cai)、線材(cai)(cai)和型材(cai)(cai)
銅工藝品
銅工(gong)(gong)(gong)藝品(pin)是(shi)一種手(shou)工(gong)(gong)(gong)藝的(de)產品(pin),即通過手(shou)工(gong)(gong)(gong)將原料(liao)或半成(cheng)品(pin)加工(gong)(gong)(gong)而成(cheng)的(de)產品(pin),是(shi)對(dui)一組價值藝術(shu)品(pin)的(de)總稱。銅工(gong)(gong)(gong)藝品(pin)來源與生活(huo)(huo),卻(que)又創造了高于生活(huo)(huo)的(de)價值。
銅樂器
銅管樂器:是(shi)一種將氣流吹(chui)進吹(chui)嘴之后(hou),造成嘴唇(chun)振動的樂器。
青銅樂器:是夏商周三(san)代(dai)音樂文化中最(zui)具(ju)代(dai)表性、最(zui)重要的歷史遺存。青銅樂器主要有銅鈴、鉦、鐃、鎛、編甬鐘(zhong)、編鈕(niu)鐘(zhong)等。
水(shui)洗、除塵(chen)、藥洗、涂層要(yao)得當。銅制(zhi)品大部分都需(xu)要(yao)進行(xing)清潔處理(li),主(zhu)要(yao)是除掉銅制(zhi)品上的污垢(gou),如(ru)土斑、銹斑、油(you)垢(gou)、汗(han)漬等,因為(wei)這些東西不(bu)但損害(hai)銅制(zhi)品,還可能對身體不(bu)好。
1、除塵:笨重銅制品可利用吸塵器清除銅制品上的灰塵要用軟布、軟毛刷、軟毛撣子等。對體積較大、笨重且不規則的銅制品,可采用吸塵器等機械進行除塵;對有鏤空結構或縫隙的銅制品,在吸塵的同時也可以使用高壓氣泵,將吸塵器不易吸除的塵土吹落。
2、藥洗:倍半碳酸鈉洗去青銅病要經常觀察青銅制品的變化,一旦發現青銅病癥發生,要及時處理,可以使用倍半碳酸鈉(5%碳酸鈉+碳酸氫鈉)清洗;遇到一些銹腐嚴重的銅制品,以及混有其他雜物的銅制品,應請專業人員進行清洗。
3、涂層:涂層有機硅比涂石蠟好干凈的銅制品,傳統保存方法是涂上一層石蠟,但這樣容易堆積灰塵,就不美觀了。對此,可在銅制品上涂一層有機硅將其密封,這樣能更有效地防止有害氣體、灰塵。總的來說,存放和陳列古玩的房間要保持干凈,保持空氣清潔;同時注意遠離廁所、污水坑、鍋爐房、煤廠等易產生污染與灰塵的地方;最后室內最好用暖氣設備取暖,暖氣片要遠離銅制品收藏柜。